CRYSTAL

METHAMPHETAMINE

(ICE)



OVERVIEW

ICE is the latest nightmare of the growing list of designer drugs. It is a comparatively new form of methamphetamine recently introduced into the U.S. Named for its ice-like appearance, ICE is the crystalline form of d-methamphetamine hydrochloride (HCI).

Unlike cocaine, which is derived from the coca plant and chemically processed, ICE is synthetically produced from chemicals. While distinctive in its rock crystal appearance, ICE is chemically identical to the powder and tablet forms of methamphetamine.

ICE is typically smoked in a glass pipe where it is melted, vaporized, and inhaled to give an almost instantaneous rush directly to the brain. Although more expensive than cocaine on the street, ICE is effectively cheaper since it produces highs lasting from 12 to 24 hours compared to 20 minutes for cocaine; moreover, the portion remaining after a "hit" can be cooled down and reused.

The ill effects of ICE are severe and extensive. It can be instantly addictive and has an enormous range of harmful effects on the mind and body, including death.

The wide range of toxic chemicals used in the manufacture of ICE result in dangerous and long-lasting effects to the environment. These include hazardous and illicitly-dumped waste, polluted water, and heavily contaminated laboratory sites. The clandestine laboratories are abandoned for reasons of either accumulating danger to the operators or avoidance of eventual detection.

While a number of elements of logistic evidence can suggest the existence of an illicit ICE lab, the toxic hazards of on-site investigation by law enforcement officers require specially-trained personnel wearing protective clothing to insure safety.

In view of the comparatively early stage of its production and usage, ICE distribution is fragmented and non-centralized and its potential has not yet been recognized or exploited by Organized Crime.

Similarly, the Federal government has yet to develop a national strategy for ICE suppression. Accordingly, a timely, coordinated and comprehensive plan could well seize the initiative from Organized Crime and prevent ICE usage from reaching the proportions of cocaine.



ICE

Within the last several years, the term "ICE" has become synonymous on the west coast and in Hawaii with a colorless, odorless form of crystal methamphetamine resembling broken fragments of glass, rock candy, Hawaiian salt or ice shavings.

All of the exhibits of ICE analyzed thus far by the DEA Western Regional Laboratory have been d-methamphetamine hydrochloride (HCI) with purity levels of 90-100%. For the purpose of this report, all references to ICE, unless otherwise stated, will refer to the large clear rock-like crystals of d-methamphetamine HCI.

Until recently, ICE had been produced exclusively in the Far East. In point of fact, methamphetamine, the first amphetamine derivative of any significance, was synthesized in 1919 by a Japanese chemist. It was in post-World War II Japan that methamphetamine use became prevalent.

Production of crystal methamphetamine has occurred in the Far East, principally in Korea, for many decades. Intensified Korean law enforcement efforts applied in recent years appears to have forced Korean laboratory operators to shift their operations to Taiwan and possibly the Philippines.

Attempts to smuggle ICE from Taiwan and Korea into Hawaii can be documented back to the mid-1980's. In the summer of 1988, its use became relatively widespread in Hawaii, and paralleled the crack summer of '88 in the continental United States.

There is no indication that, when ICE was first imported from the Far East into Hawaii, there were efforts underway to distribute it as a new drug. Now, however, ICE is sold under the misconception that it is the only smokeable form of methamphetamine. The drug's rapid onset of action (estimated to be approximately seven seconds) is similar to that of crack. The duration, however, of the euphoric effect is reported to last much longer. It is not uncommon for the effects of ICE to last for as long as 12 to 24 hours.

The going wholesale price for ICE in Hawaii is $65,000 per kilogram or $40,000 a pound. Prices for ICE at the retail level are comparable to those for heroin. The retail level prices for domestic ICE are as follows:

Ounce $3,600 - $7,000

1/2 ounce $2,000 - $4,000

1/4 ounce $1,000 - $1,250

1/8 ounce $800 - $900

1 gram $200 - $400

1/2 gram $150 - $250

1/4 gram $100 - $150

10 gram $50

a paper $50

Distribution of ICE is rapidly presenting the same problems to Hawaiian law enforcementofficers that crack did in many metropolitan areas of the continental United States in its prevalence and addiction potential.

Although, as stated earlier, there has been a great deal of publicity concerning this form of crystal methamphetamine, actual distribution at this time appears to be somewhat limited.

The trafficking of ICE from the Far East to Hawaii began in 1984 when U.S. undercover agents and members of the Yamaguchigumi Group of the Yakuza (Japanese organized crime) arranged for the delivery of 40 kilograms of ICE and eight kilograms of heroin to Honolulu. A Chinese national residing in Hong Kong was arrested upon arrival in Honolulu for possession of 15 pounds of ICE. That was the first documented seizure of ICE.

One of the largest ICE distribution networks discovered is of Korean chemists. It is believed they operated a clandestine laboratory in the Portland, Oregon area which funneled multi-kilogram quantities of ICE via Seattle, Washington to a Filipino smuggling network based in Hawaii. Additionally, Korean chemists operating out of Taiwan also provided ICE to this same distribution network.

On October 12-13, 1989 DEA agents on the East Coast effected the arrest of two Korean violators and seized 900 grams of ICE. Information indicates that the ICE was smuggled from Korea.

A controlled delivery of ICE was made to Bozeman, Montana from LAX airport on September 29, 1989, with subsequent delivery to Gallatin Field, Montana. Two individuals were arrested and 1/2 gram of ICE was seized.

Preliminary investigative review has indicated areas of distribution include Seattle, Washington; Portland, Oregon; Los Angeles, San Francisco (including Contra Costa and Solano Counties, Haight Asbury, Sacramento, Polk Gulch and Fort Mason areas) and San Diego, California.

In many areas of the country, the term crank, speed or crystal is used interchangeably to describe methamphetamine; however, regional variations exist. White powder may be called crystal while the term "crank" or "speed" distinguishes the pill variety of methamphetamine. In Honolulu, however, crank refers to the powdered form of methamphetamine and the term crystal connotes "ICE" or the rock form of crystal methamphetamine.

Other terms used to refer to ICE include:

a. quartz

b. glass

c. Shabu (Japanese)

d. Kaksonjae (Korean)

e. Hiropon (Korean)

f. Batu (Filipino Tagalog word meaning rock)

g. crack meth

h. ice cream

Methamphetamine is sold in glass vials, paper bundles, or clear heat-sealed cellophane packets. Common paraphernalia include syringes for the user who injects his drugs and glass smoking pipes.

Users refer to smoking ICE as a "cool smoke" as opposed to a "hot smoke" associated with crack smoking. The reasoning behind this may be that the vapor produced from heating the crystal methamphetamine is white or clean as opposed to the "dirty" brown color produced from smoking crack. Moreover, because methamphetamine has a lower melting point, it does not require as much heat to be applied. An ICE user reportedly can take a hit or two, then wrap the pipe in a cold towel or paper, thus, recrystallizing the residue for future use.

Several factors are believed to contribute to the growing popularity of ICE.

* it is similar in quality to, or better than, meth for injection

* smoking ICE eliminates the use of a needle

* it enters the body faster when it is smoked

* its effects are long lasting when compared to other drugs

* it is odorless, colorless and tasteless

* it is easy to transport

* it sells for more than cocaine but is cheaper to produce

ABUSE

When methamphetamine is smoked it is extremely volatile. That volatility delivers a highly concentrated dose of pure d-methamphetamine HCI instantaneously to the brain via the lungs. The effects are believed to be even more intense than with crack because of the chemical property and the lower melting point of methamphetamine. ICE may be addictive with practically the first smoke and can be fatal.

The most dramatic effect of this drug use is weight loss. Paranoia and hallucinations follow with much variation according to user tolerance. Psychotic breaks often result in users entering treatment programs. Other side effects such as rapid respiratory and cardiac rates and increased body temperature were reported in many cases, also complaints ranging from mild anxiety to acute hypertensive crisis, and violence.

Most frequently, the principal feature is an acute psychosis in chronic users, with auditory hallucinations and extreme paranoia. Often these patients demonstrate destructive behavior. Most patients coming into the emergency room are suffering from drug-induced psychosis and violent behavior similar to the effects of cocaine.



HOW TO IDENTIFY

Methamphetamine is normally found as a white powder or as a translucent crystal similar in appearance to "rock candy" or Hawaiian salt. "Rock crank" is a very pure form of methamphetamine. Chemists allow their finished product to dry into huge crystal chunks which are broken into ounce rocks and left uncut for sale. The color and consistency of the final product is usually determined by the formula and amount of washing. As an example, green meth is the result of reaction done in a copper hydrogenator.

Most prevalent is the translucent or clear rock crystal. This form of meth is said to be water based and burns quickly leaving a milky white residue. Reports also show that a yellowish crystal meth is also available. This form of meth is said to be oil based. Yellow meth is also said to burn slower and last longer leaving behind a brownish or black residue.

PARAPHERNALIA

The methamphetamine pipe has only one section where the methamphetamine is placed and heated. There are no screens and no coolants in the meth pipe. The pipes used for smoking meth usually have a hole on the top of the bowl leading to the main chamber and may have a vent hole on the stem between the chamber, where the crystal is placed, and the mouthpiece.

A small amount of ICE is placed into the chamber and heated with a lighter or other heat source until it turns to a liquid and, subsequently, a vapor. The opening in the chamber and vent hole is sealed, usually with a finger, while the crystal is being heated. Once the crystal has turned to a vapor, it is inhaled by the user. An ICE smoker can often be identified by the telltale burn mark on the finger used to seal the hole in the main chamber.



CLANDESTINE LABORATORY DEFINED

A clandestine laboratory is a covert or secret, illegal operation that produces a controlled substance through the synthesis of raw chemicals. This is accomplished through the use of specific laboratory glassware and apparatus or make-shift "cooking" pots, depending on the sophistication of the operation.

Set-up of labs is preferable in rural areas because of laboratory smells, consumer comings and goings, and occasional explosions are less likely to draw attention in the country. However, clandestine labs can be found anywhere; houses, apartments, farmhouses, abandoned buildings, cars, moving vans, almost any imaginable place is a candidate.

Clandestine laboratories may be categorized into four general types based on the type of process that is required. These types are:

1. Extraction: the raw plant material is changed into a finished drug product by the use of chemical solvents. The chemical structure of the drug is not altered.

Examples:

Cannabis to hashish

Hashish to hashish oil

Opium to morphine

2. Conversion: a raw or unrefined drug product is changed into a finished or refined drug. Here the chemical structure is changed. Examples:

Morphine to heroin (diacetylmorphine)

Cocaine base to cocaine hydrochloride

3. Synthesis: a combination of proper raw materials in required portions results in a finished drug product through chemical reaction:

Examples:

Chemicals to methamphetamine (speed, crank),

phencyclidine, LSD, etc.

4. Tableting: the machine processing of the final drug product into a dosage unit form (tablet).

CLANDESTINE LABORATORY NEEDS

1. Privacy to conceal the illegal activity itself. Operations are at odd hours and include foot and vehicular traffic; machinery noise if using a tablet press; and most important, concealment of chemical odors.

2. Utilities such as water, electricity and gas. This will depend upon the type of drug being manufactured as specific drugs require some, all, or none of the foregoing.

3. Basic raw materials (chemicals).

Law enforcement officers should be aware that lab activity may be ongoing if they

come across unusual activity such as:

1. Continuous night operation not usual in the neighborhood.

2. Large fans on property.

3. Unusual odors, etc.



ENVIRONMENTIllegal drug labs are creating a toxic-waste nightmare. Labs set up in rented houses, motel rooms and remote forests are leaving a trail of tons of discarded, dangerous chemicals. The chemical raw ingredients range from toxic substances such as hydrogen-chloride gas and lead acetate, to explosive and inflammable materials as ether and red phosphorous. The U.S. Drug Enforcement Administration (DEA) is spending some $5 million to $8 million annually to have private contractors haul waste from raided labs.

The wastes are not only a serious long-term problem, but also an acute hazard to law enforcement officers who carry out raids on the labs.

Adding insult to possible injury, the enforcement agencies find that raiding a lab can make them responsible for its waste. The Environmental Protection Agency (EPA) even ruled that the DEA is technically the "generator" of meth lab waste that it discovers, making DEA legally liable for the cleanup.

Many believe that the best way to cut into the meth market and the waste it produces is to restrict sales of the so-called precursor chemicals used to make methamphetamine. Several states now require dealers to get permits to sell these chemicals and keep records of exactly who is buying them. Congress put similar record-keeping requirements in last fall's drug law.



OFFICER SAFETY

Several chemicals involved in methamphetamine production present a danger of injury from fire or explosion. At the lab site there are possible risks of exposure to infectious disease in the event of skin puncture by drug paraphernalia. In addition, risk of injury or toxicity from chemical exposure may occur by inhalation, skin exposure, or ingestion.

Inhalation and/or skin exposure should be of significant concern to officers exposed to the clandestine laboratory environment. Inhalation or skin exposure may result in injury from corrosive substances, with symptoms of shortness of breath, cough, chest pain, etc., or burns to the skin. Many solvents are well absorbed by the lungs into the body, and if the dose is sufficient, may result in symptoms of intoxication, dizziness, nausea, etc.

The skin, to a lesser extent, may also absorb some solvents if chemicals remain in direct contact for a significant amount of time.

Drugs produced in clandestine labs contain a plethora of contaminants and by-products which do not have predictable side effects. As chemical controls become more prevalent, it may be anticipated that the clandestine chemist will resort to more

exotic methods of production, resulting in the creation of contaminants and by-products with unexpected and potentially serious adverse effects with whom the chemicals come in contact.

Active Lab

A laboratory that is functioning and supplied with chemicals presents the greatest risk of adverse health effects for occupants and emergency responders. If a building is discovered to be a clandestine drug lab containing chemicals and laboratory hardware, it should be considered unsafe for entry except by trained personnel utilizing appropriate personal protective equipment.

However, should exigent circumstances prevail, and entry must be made into the lab:

DO NOT TURN ANYTHING ON OR OFF

DO NOT TOUCH ANYTHING

DO NOT SMOKE AT THE SCENE

DO NOT USE PORTABLE RADIOS OR ELECTRONIC DEVICES

WHILE IN CLOSE PROXIMITY OF THE LAB



Danger of explosion and fire comprise the greatest risk from chemicals due to large amounts of solvents that may be present upon entering the building. A large accidental or deliberate spill of chemicals could result in ambient air concentrations great enough to produce symptoms from inhalation of solvents, corrosives, or cyanide. The lab cooking process may generate airborne contamination which could result in significant amounts of toxic gases being inhaled as well.

Ambient concentrations of chemicals have not been measured at the active clandestine lab environment and may vary considerably depending on the lab process and quantity of chemicals present. A potentially serious risk of chemical exposure may occur in the event that occupants set up chemical "booby traps" in an effort to injure or disable potential intruders.

Acute injury with immediate onset of symptoms from a massive chemical exposure is the most significant health risk related to methamphetamine manufacture.

Fire, explosion, inhalation of fumes and skin contact with chemicals are the most immediate dangers in an operating laboratory or a lab dump site. Fumes from many of the chemicals are explosively flammable, therefore, electrical sparks and open flames should be avoided. Do not flip switches or pull electrical plugs from outlets. Extinguish all pilot lights on water heaters and stoves. Anyone near an illegal laboratory should wear personal protective clothing.

Concentrated inorganic acids such as hydrochloric, sulfuric, and nitric, are generally found in laboratories. Skin contact with these acids results in severe burns and inhalation of vapors causes irritation of mucous membranes and respiratory tract. These acids are water soluble and can be washed away with large amounts of water. Baking soda can be used to neutralize the action of the acid.

Strong bases such as sodium hydroxide (lye) and methylamine are another group of chemicals found in laboratories which are a hazard. Skin contact and inhalation should be avoided because of their corrosive nature. Washing with large amounts of water may not always remove the base; it may be necessary to wash with a weak acid solution such as vinegar or boric acid.

In some synthesis, such as methamphetamine and phencyclidine (PCP), the actual reaction apparatus may be minimal, involving only a container and a stirring mechanism. In more complex synthesis, law enforcement officers may encounter laboratory equipment set up to accommodate reaction steps that may involve high pressure, vacuum, heating, or cooling.

If compressed gas is being fed into the setup, it can be shut off at the main valve at the top of the gas cylinder. The regulator off to the side of the tank serves to stepdown the pressure from the tank to that required for the reaction. If there is a pressure gauge built into the regulator, a gradual but complete drop in pressure will signal that the system is at atmospheric pressure and the danger is reduced.

If the reaction apparatus is under vacuum, the vacuum pump can be shut off. After perhaps 15 to 30 minutes, enough air will leak into the system so that the vacuum hoselines between the pump and reaction systems can be disconnected.

Many chemical reactions require an external source of heat. Most often the heat will be supplied electrically by a hot plate or heating mantle. Turning off the heat supply should cause the reaction to gradually come to a halt. If the reaction apparatus is fitted with a cooling condenser, do not turn off the coolant (usually tap water) until the apparatus has reached room temperature.

A chemical reaction that produces heat is a more hazardous situation. The reaction should be allowed to go to completion before the coolant is removed. The reaction can be packed in ice for transport. The reaction apparatus should be at room temperature and atmospheric pressure before attempting to dismantle any of the interconnected pieces of apparatus.

There are a number of particularly hazardous compounds which deserve specific recognition.

1. ETHER, an extremely flammable liquid, tends to form explosive peroxides especially when evaporated to dryness. Empty or nearly empty ether cans should be handled with extreme caution. Peroxides may be removed by shaking ether with 5% aqueous ferrous sulfate.

2. LITHIUM ALUMINUM HYDRIDE can be used in the synthesis of amphetamine, methamphetamine, mescaline and DMT. Lithium aluminum hydride is a highly unstable compound which reacts violently with moisture or heat. To prevent fire and/or explosion, it is imperative to keep any moisture (even that in the air and on skin) or source of heat away from this reagent. VITRIDE has recently replaced lithium aluminum hydride in some laboratories. It should be handled with the same precautions as LITHIUM ALUMINUM HYDRIDE.

3. MERCURIC CHLORIDE (or BROMIDE) are violent poisons. Avoid breathing the dust of these chemicals. Skin contact will result in retention of these compounds in the body forever.

4. SODIUM (or POTASSIUM) CYANIDE is used in the synthesis of PCP and phenylacetic acid (chemical used to make speed). When they come in contact with acid, cyanide easily form hydrogen cyanide gas, the gas used in gas chambers. Hydrogen cyanide gas has the odor of almonds. Even when the solid crystals of cyanide are present, make sure the area is well ventilated.

5. RANEY NICKEL, which is used as a catalyst in the synthesis of amphetamine and cocaine, should be handled with extreme care. Raney Nickel ignites on contact with air. It should be stored in alcohol, ether, or water.

6. SODIUM is a soft shiny metal which, when exposed to air, becomes dull gray. Sodium reacts violently with water.

7. HYDRIODIC ACID, which is a reducing agent used in the ephedrine method of producing methamphetamine, is extremely corrosive and can cause major tissue damage, respiratory collapse and death.

Although the risk of acute injury is possible from exposure to chemicals at an active lab site, risk of chronic toxicity or carcinogenesis is remote. Chemically induced cancers only occur following long term exposures in the industrial setting.

Former Lab

After removal of the illicit laboratory equipment and chemicals, residual amounts of some substances may persist on building surfaces and furnishings prior to cleanup or decontamination.

Some of the dangerous chemicals include:

Phenyl-2-Propanone (P2P) which penetrates deep into wood, sheet rock, and any porous material, making it extremely difficult to remove.

Phosphine gas created by the reaction between red phosphorous ephedrine, and is 33 times more deadly than cyanide.

White phosphorous (produced when red phosphorous is overheated), is flammable if exposed to air, and can cause bone cancer and liver disease.

To cleanup a residence that once contained a meth lab, one generally has to remove the wallpaper and wallboards, scour all the walls, floors, and ceiling, replace the carpet, repaint inside several times, steam clean, and possibly even "bake out" the chemicals.

Substances present in the active lab as gases or volatile solvents will dissipate rapidly with ventilation unless large amounts of liquid remain due to a spill. Residual solids in the form of surface residues, spills, etc. are water soluble and, therefore, can be decontaminated by water and detergent cleansing.

If recommended decontamination procedures are followed, re-occupancy should be possible. Based on known physical properties of the chemicals associated with methamphetamine production, there is not current scientific evidence to suggest a continuing human health risk after decontamination.



ON-SITE FIRST AID

Treatment

* Vapor exposure: Persons exposed to vapors should be removed to fresh air. Specific decontamination procedures such as chemical rinses are not indicated.

Chronic vapor exposure to some chemicals may produce a disagreeable odor on the clothing of the building occupants. Therefore, it may be advantageous to remove contaminated clothing from building occupants at the site, if possible, to prevent spread of odor. The presence of a chemical odor on a person removed from the laboratory environment does not imply that there is a health risk to emergency responders, (i.e., police, fire, EMT). However, when medical care is not required, transport may be accomplished by providing a plastic suit to control spread of odor.

* Skin exposure, liquids: A spill or splash of liquid substance onto the skin or eyes should immediately be irrigated with clean running water for 15 minutes. Irrigation should be followed by soap and water washing for skin exposures. If direct chemical contact has occurred, clothing should be removed immediately to allow for effective irrigation and cleansing and to prevent further exposure. Attempts to neutralize acids or alkalis should not be attempted.

* Skin exposure, solids: Direct exposure to such as powders or granules should be brushed off as much as possible and the clothing removed. The involved areas should then be irrigated and washed. Any persons with persistent symptoms should receive a medical evaluation following decontamination. Waste water from the irrigation procedure may be discarded without special treatment.

* Ingestion: Risk of toxicity is very high if chemical substances are accidentally or intentionally ingested. The nearest Poison Center should be consulted immediately for treatment recommendations following an oral ingestion.

Personal Protective Equipment

Law enforcement officers entering an active lab environment should utilize air flow respirators that will provide adequate protection against life threatening ambient concentrations of vapors. The face, eyes, and skin should be protected against chemical spills and splashes by adequate protection, including face shield or goggles. Persons handling equipment or containers should protect the hands and exposed areas of the skin by wearing impervious gloves and suitable body protection.





CONCLUSION

ICE is the drug of choice in Korea and Japan. It has already devastated Hawaii, but is only getting started in the mainland U.S. where it is still far from displacing cocaine as the most widely-used drug.

Actual ICE distribution in the mainland U.S. has, to date, been limited, but growing. It has already spread to Seattle, Portland, San Francisco, Los Angeles, and San Diego, with some usage seen elsewhere including Oklahoma, Arizona and Washington, D.C.

If the cocaine supply in the U.S. is slowed or stopped, the abusers will look for an alternative - ICE is clearly the logical choice, since it can be produced locally without import and has many advantages over cocaine its production, transport, and use.

It is particularly significant to note that to date, the only factor preventing synthetic narcotics, i.e., ICE, from becoming our leading drug crisis, is the fact that cocaine in various forms still commands the U.S. market. Should current efforts curtail the flow of cocaine into the United States, methamphetamine could serve as the logical replacement.

Since cocaine, for the most part, is chemically processed outside of the United States, the emergence of methamphetamine as a drug of choice would significantly impact on the number of clandestine laboratories encountered by law enforcement personnel.

With this, not only will law enforcement officers face increased danger and added risk in apprehension, but also in the areas of search and seizure, and asset forfeiture.